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天文学家喜欢用新望远镜观察知名天体,因为他们总能看到新事物。当天文学家使用安装在 ESO 的阿塔卡马探路者实验(APEX)上的新型SuperCam仪器时,就会发生这种情况。天文学家设计该仪器来检查猎户座分子云复合体中的分子云和恒星形成区域以及其他目标。 该图像是 APEX 大型 CO 外差猎户座遗产调查 (ALCOHOLS) 的一部分。虽然这张图片是几年前的照片,但它只是在最近才被处理并包含在新发表的论文中。 论文的标题是“ APEX 大型 CO 外差猎户座遗产调查 (ALCOHOLS)。I. 调查概述,”主要作者是 Thomas Stanke。该论文将发表在《天文学和天体物理学》杂志上。 作为他们观察的一部分,这项工作背后的团队观察了火焰星云及其周围的其他结构。他们很好地观察了反射星云 Messier 78 和 NGC 2071,它们被附近的恒星和其他物体(如膨胀的气泡)照亮。 在宣布这项研究和新图像的新闻稿中,主要作者托马斯斯坦克说:“正如天文学家喜欢说的那样,只要有新的望远镜或仪器,就观察猎户座:总会有新的和有趣的发现!” 他们的一个发现是一个小的球形云,他们称之为牛星云球。尽管它在光学结构上看起来像彗星,但它实际上是一个圆形的,可能是球形的气体云。它也是无星的。 但火焰星云(NGC 2024)是这些新图像中的一个亮点。它距离我们大约 900 到 1500 光年,位于猎户座带东端的三合星系统 Alnitak 照亮了它。 火焰是一种发射星云,这意味着气体被来自 Alnitak 的紫外线能量电离,并发出不同波长的光。就像它所属的猎户座云复合体一样,火焰星云是一个活跃的恒星形成区域。一群年轻的恒星位于火焰星云的中心,其中许多都有原行星盘。但是,也许可悲的是,这些圆盘中的许多可能永远没有机会形成行星。哈勃望远镜在 2021 年的观测表明,附近的年轻恒星正以其强烈的辐射侵蚀许多这样的圆盘。 猎户座复合体是一个错综复杂的空间区域,充满了恒星和气体,以及两者之间的所有相互作用。它是最近的大质量恒星诞生区,到处都是年轻恒星和原恒星,所有这些都经过多次调查、观察和研究。这项研究为所有这些知识增加了更多细节,作者希望未来的研究能够揭示更多。该研究的结论说,他们只是“触及”了他们的方法可以揭示的东西。 但是现在,我们可以欣赏这些图像。
黄耀曾发表论文220多篇,多发表于国际著名期刊上;他还撰写内部资料20多篇,与他人合编书籍5种,合译书籍5种。 主要论著有:1Chang-Kong Chuang,Yu-Lin Tien und Yao-Tseng Huang.Synthesenmittels cyclischer Ketonsaure-ester I. Mitteil. Synthese von 2-Methyl-cyclohexan-essigsaure-(1)-carbonsaure-(2)und verwandten Verbindun-gen.Chem.Ber.,1935,68:864-879.2Chang-Kong Chuang,Yu-Lin Tienund Yao-TsengHuang·Synthetische Studieninder Ster in-und Sexua1hormon-Gruppe I. Mitteil.Synthese eines10-Oxy-3-oxo-hexahydro-chrysens und seines Methy-lathers.Chem.Ber.,1937,70:858-863.3Yao-Zeng Huang,Kuo-Hao Lin and LiangLi.Chemical StudiesonAmino-Acids and Their Derivatives.IX.Syn thes is of Valine,Leucineand Norleucine.J.Chinese Chem.Soc.1947,15:38—45.4Yao-Tseng Huang.Y.W.Yieh and I.Chang.Phenylthiourethans asLocal Anesthetics .Brit. J. Pharmacol.,1947,3:297-299.5Yao-Tseng Huang.Synthes is of Substances Related to Tetracyclines.Tetrahedron,1960,11:52-59.6黄耀曾,戴立信,倪大男等译.有机化学中的空间效应(M.S.Newman原著).北京:科学出版社,1964.7卢嘉锡,黄耀曾,曾广植等译.化学键的本质(L.鲍林原著).上海:上海科学技术出版社,1966.8Yao-Zeng Huang,Ji-SenLi,Jian-Qiang Zhou,et a-l.Oligomerization ofPerfluoropropylene Catalyzed by π-Bis(Arene) Chromium(O).J. Organomet . Chem.,1981,218:169—175.9Yao-Zeng Huang and Yan-Chang Shen.Arsonium Ylides.Advancesin organometallic Chemistry,1982,20:115-157.10Yao-Zeng Huang,Yan-Chang Shen,et al.A Novel Acetylenic Ester-Vinyl Ether Rearrangement.Scientia Sinica,SeriesB,1982,25(5):587-593.11M Tsutsui,Y.Ishii and Yao-Zeng Huang.Fundamental Research in Organometallic Chemistry(Proceedings of the China-Japan-United States Trilateral Seminaron Organometallic Chemistry heldin Beijing,June,1980).New York:Van Nostrand Reinhold Company;Beijing:Sci-ence Press,1982.12Yao-Zeng Huang,Akio Yamamoto,Boon-Keng Teo.New Frontiers inOrganome tallici and Inorganic Chemistry(Proceedings of the Second China-Japan-U.S.A.Trilatera1 Seminar on Organometallic and Inorgan-ic chemistry held in Shanghai,China,June1982).Beijing:Science Press,1984.13Yao-Zeng Huang,Jisen Li,Qilin Zhou,et al.Polymerization of Perfluoro-2-alkynenitriles by π—Bis(benzene)chromium(O).J.Polym.Sci,Polym.Chem.Ed.1985,23:1853—1859.14Yan-Fang Wang,Jin-CuiLi,Yao-Zeng Huang,et al.A Facile Stereoselective Synthesis of Leukotriene A4(LTA4)Methyl Ester.TetrahedronLett.1986,27:4583——4584.15Li-Lan Shi,Weng-Juan Xiao and Yao-Zeng Huang.The use of Arsorane as Isoprenoid Reagent Synthesis of 5-Substituted-3-methyl2.4-Penta-dienoic Esters(ABA Ester Analogs).Synthesis,1987,370—371.16Huaiyu Sheng,Shouyuan Lin and Yao-Zeng Huang.Palladium Catalyzed Rearrangement of 2—Alkynyl Aryl Ketones to Substituted Furans.Syn-thesis,1987,1022-1023.17Yao-Zeng Huang and Qi-Lin Zhou.Nickel-,Palladium-and Platinum-Catalyzed Reactions of Perfluoro-and Polyfluoroalkyl Iodides with Ter-tiary Amines.J.Org.Chem.,1987,52:3552—3558.18Yao-ZengHuang,Li-Lan Shi,JianHua Yang,etal.Highly Stereoselec-tive Synthesis of(Z.E)ConjugatedI)iene Type Sex Pheromone.J.Org.Chem.,1987,52:3558—3560.19Yao-Zeng Huang,Changtao Qian and YuanyaoXu.Progress of Org-anomentallic Chemistry.In: Advancesin Science of China, Chemistry.Tang Youqi(ed.)Beijing:Science Press; New York:John Wiley and Sons,1987.Vol2:91—124.20Yao-Zeng Huang,Li-Lan Shi and Snao-Wei Li.An Efficient and Stere-oselective Synthesis of(E)α-Enonesvia Arsonium Salts.Synthesis of the Key Intermediates of Brassinosteroid and Prostagl and in.Synthesis,1988,975—977.21Yao-Zeng Huang and J.Q.Zhou.Reductive Defluorination of Perfluoro-propylene Trimer and Perfluoro-,△9(10)-octaline by “Cr-H”.J.Organomet.Chem,1988,348:235—239.22Qilin Zhou and Yao-Zeng Huang.A Facile Method for Fluoroalkylationof Aniline and Its Derivatives.J.Fluorine Chem.,1988,39:87-98.23Qilin Zhou and Yao Zeng Huang.A Convenient and General Synthes is of 2-Alkyl-3-fluor-3-opolyfluoro-alkyl-2-propenal J.F1uorine Chem.,1988,39:323-327.24Li-Lan Shi,Wei-Bo Wang,Yao-Zeng Huang,et al.The First Exampleof A Catalytic Wittig-Type Reaction.Tri-nbutyl-arsine Catalyzed Ole-fination in the Presence of Triphenyl phoIphite.J.Org.Chem.,1989,54:2027—2028.参见CHEMTRACTS-ORGANIC CHEMISTRY1989,2:300—301.25Li-Lan Shi,WeiBo Wang and Yao Zeng Huang.A Novel Synthesis of2,3-Epoxy-3-arylpropanol via Arsonium Salt.Tetrahedron Lett.1989,29(41):5295—5296.26Yao-Zeng Huang,Li-Lan Shi,Jian-Hua Yang,et al.Facile Synthesesof Unsaturated Aldehydes,Ketones,Amides and Related Natural Pro-ducts via Arsonium Sa1ts.Heteroatom CheImistry.VCH Publishers,Inc.,1990,189—206.27Wei Bo Wang,Li-Lan Shi and Yao Zeng Huang.Efficiant SbCl3-MetalSystem for Allylat1on,Reduction and Acetaliz ation of Aldehydes.Tetrahedron,1990,46(9):3315—3320.28Yao-Zeng Huang,Yi Liao and Chen Chen.Reactionof Carbonyl Com-pounds with Benzyl trialkyl stibonium Bromide Mediated by Different Strong Bases.J.Chem.,Soc.Chem.,Commun.,1990(1):85—86.29Yi Liao,Yao-Zeng Huangand Fang-Hua Zhu.Selective Acetalization ofAldehydes with Trialkoxystibine using Allyl Bromide.J.Chem.Soc.Chem.Commun.,1990(6):493—494.30Jian-Hua Yang,Li-Lan Shi,Yao-Zeng Huang,etal.Facile Synthes isof 2.4-Diena1svia Arsonium SaltandIts Application To ward SomeNatural Products.Heteroatom Chemistry,1990,1:75-—81.31Yao-Zeng Huang and Yi Liao.On Pentaalkylstiborane. Syntheses of Ho-mobenzylic Alcohols,Homoallyl Alcohol,Ethyl5-Aryl-5-hydroxy-2-pentenoates and β-Hydroxy-propionic Acid Derivativesvia Pentaalkyl-stiboranes.J.Org.Chem.,1991,56(4):1381-1386.32Yao-Zeng Huang.The Chronicle of My Scientific Study Reviewson Heteroatom Chem.1995,12:1—21,MYU,Tokyo,Japan.
TeachingstudentsaccordingtotheiraptitudeinhighervocationalpharmaceuticalchemistryteachingapplicationPickto:thearticlefromourrealityofthedrugbusinessandmanagementinhighervocationalcollegeofpharmaceuticalchemistrymajor,howtodowelltheteachingorientationofhowstudents'professionalintroductionandrelatedchemicalknowledge,broadenthestudents'visualAngle,thispaperdiscusseshowtothepharmacyinhighervocationalteachingofmedicinalchemistryinaccordancewiththeiraptitude,andtheimportanceofteachinginhighervocationalteachingstudentsaccordingtotheiraptitude.
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Chem.2006,71(24), 9241-9243.(55)Ma C*, Ding HF,Wang YG, Novel Annulation Reactions of Aryl Methyl Ketenes with Zwitterions Derived from Dimethyl Acetylenedicarboxylate andN-Alkylimidazoles,Org. Lett.2006,8(14), 3133-3136.(56)Wang L, Zhang YH*, Liu LF,Wang YG*, Palladium-Catalyzed Homocoupling and Cross-Coupling Reactions of Aryl Halides in Poly(ethylene glycol),J. Org. Chem.2006,71(3),1284-1287.(57)Cui SL, Lin XF,Wang YG*, Cascade Reactions of Aromatic Aldehydes with Electron-Deficient Acetylenes: Regioselective Construction of Diverse Aromatic Ring Systems,Eur. J. Org. Chem.2006,(22), 5174-5183.(58)Zhou FY, She J,Wang YG*, Synthesis of a benzyl-protected analog of arenarioside, a trisaccharide phenylpropanoid glycoside,Carbohydrate Res.2006,341, 2469-2477.(59)Yang YY, Shou WG,Wang YG*, Synthesis of beta-amino carbonyl compounds via a Zn(OTf)2-catalyzed cascade reaction of anilines with aromatic aldehydes and carbonyl compounds,Tetrahedron2006, 62, 10079-10086.(60)Lei M, Hu RJ,Wang YG*, Mild and selective oxidation of alcohols to aldehydes and ketones using NaIO4/TEMPO/NaBr system under acidic conditions,Tetrahedron2006,62(38), 8928-8932.(61)Li SJ, Zhong JH,Wang YG*,Synthesis of new chiral N-heterocyclic carbenes from naturally occurring podophyllotoxin and their application to asymmetric allylic alkylation,Tetrahedron:Asymmetry2006,17(11), 1650-1654.(62)Huang JY, Li SJ,Wang YG*, TEMPO-linked metalloporphyrins as efficient catalysts for selective oxidation of alcohols and sulfides,Tetrahedron Lett.2006,47(32), 5637-5640.(63)Lin XF, Cui SL,Wang YG*, A highly efficient synthesis of 1,2,3,4-tetrahydroquinolines by molecular iodine-catalyzed domino reaction of anilines with cyclic enol ethers,Tetrahedron Lett.2006,47, 4509~4512.(64)Huang, HY; Lei, M;Wang, YG*, A novel and efficient ionic liquid supported synthesis of oligosaccharides,Tetrahedron Lett.2006,47, 3047-3050.(65)Lin, XF; Cui, SL;Wang, YG*, Molecular iodine-catalyzed one-pot synthesis of substituted quinolines from imines and aldehydes,Tetrahedron Lett.2006,47, 3127-3130.(66)Shou, WG; Yang, YY;Wang, YG*, An efficient synthesis of beta-amino esters via Zn(OTf)2-catalyzed Mannich-type reaction,Tetrahedron Lett.2006,47, 1845-1847.(67)Jian SZ, Yuan Q,Wang YG*, Diastereoselective synthesis of trans beta-lactams on soluble polymer support,Synthesis2006, (11), 1829-1835.(68)Yuan Q, Jian SZ,Wang YG*, Enantioselective synthesis of beta-lactams using a chiral auxiliary,Synlett2006, (7), 1113-1115.(69)Liu LF, Zhang YH*,Wang YG, Phosphine-free palladium acetate catalyzed Suzuki reaction in water,J. Org. Chem.2005,70 (15): 6122-6125.(70)Cui SL, Lin XF,Wang YG*, Parallel Synthesis of Strongly Fluorescent Polysubstituted 2,6-DicyanoanilinesviaMicrowave-promoted Multicomponent Reaction,J. Org. Chem.2005,70(7), 2866-2869.(71)Ding HF, Ma C*, Yang YW,Wang YG*, Unexpected Reaction of Dimethyl Acetylenedicarboxylate with in Situ Generated Arylketenes Catalyzed By 1-Methylimidazole,Org. Lett.2005,7(11),2125-2127.(72)Luo CC, Zhang YH,Wang YG*, Palladium nanoparticles in poly(ethyleneglycol): the efficient and recyclable catalyst for Heck reaction,J. Mol. Catal. A: Chem.2005, 229, 7–12.(73)Shou WG, Yang YY,Wang YG*, Liquid-phase Syntheses of 2, 3-Dihydro-4-pyridones and β-lactams from PEG-supported Aldehydes,Synthesis2005, (4), 530-536.(74)Shou WG, Yang YY,Wang YG*, Parallel synthesis of strongly fluorescent tetraaryl-4,5-dihydro-1,2,4-triazoles via 1,3-dipolar cycloaddition on soluble polymer support,Synthesis2005, (20), 3535-3540.(75)Jia SZ, Ma C,Wang YG*, An Efficient and Diastereoselective Synthesis oftransβ-Lactams and β-Aminocarbonyl Compounds,Synthesis2005, (5), 725-730.(76)Li SJ,Wang YG*, A novel and selective catalytic oxidation of hydrocarbons to ketones using chloramine-T/O-2/Fe(TPP)Cl system,Tetrahedron Lett.2005,46 (46): 8013-8015.(77)Du LH, Zhang SJ,Wang YG*, Phenacyl esters as a new photocleavable linker in liquid-phase chemistry,Tetrahedron Lett.2005,46, 3399-3402.(78)Li WJ, Lin XF, Wang J, Li GU,Wang YG*, Palladium-catalyzed Michael addition of indoles to alpha,beta-unsaturated ketones in an ionic liquid,Synlett2005, (13), 2003-2006.(79)Wang L, Zhang YH, Xie CS,Wang YG*, PEG-supported imidazolium chloride: A highly efficient and reusable reaction medium for the Heck reaction,Synlett2005, (12), 1861-1864.(80)Xu G,Wang YG*,Microwave-assisted amination from aryl triflates without base and catalyst,Org. Lett.2004,6, 985-987.(81)Wang YG*, Wu XX, Jiang ZY, A mild and efficient selective tetrahydropyranylation of primary alcohols and deprotection of THP ethers of phenols and alcohols using PdCl2(CH3CN)2as catalyst,Tetrahedron Lett.2004,45, 2973- 2976.(82)Cui SL, Jiang ZY,Wang YG*, A general and efficient protocol for the synthesis of biaryl ethers from aryl silyl ethers using Cs2CO3,Synlett2004, 1829-1831.(83)Wang YG*, Lin XF, Cui SJ, An efficient protocol for the liquid-phase synthesis of furanoquinolines and pyranoquinolines,Synlett2004, 1175-1178.(84)Wang YG*, Zhang J, Lin XF, et al. Parallel synthesis of pyrazolines on soluble polymer support,Synlett2003, (10), 1467-1468.(85)Lin XF, Zhang J, Cui SL,Wang YG*, Poly(ethylene glycol) supported liquid-phase synthesis of 1,2,4-oxadiazolines,Synthesis2003, (10), 1569-1573.(86)Shang YJ, Shou WG,Wang YG*, Synthesis of 1,2,4-oxadiazolines on soluble polymer support,Synlett2003, (7), 1064-1066.(87)Lin XF, Zhang J,Wang YG*, Parallel synthesis of 4,5-dihydro-1,2,4- oxadiazoles using soluble polymer support,Tetrahedron Lett.2003,44(21), 4113-4115.(88)Jiang ZY,Wang YG*, A mild, efficient and selective deprotection of t-butyldimethylsilyl-protected phenols using cesium carbonate,Tetrahedron Lett.2003,44(19), 3859-3861.(89)Lin, XF; Cui, SL; Wang, YG,Rapid one-pot solid-phase synthesis of 1,2,4-oxadiazolines,CHEM. LETT.2003, 32 (9), 842-843.(90)Jiang, ZY; Wang, YG,A mild, efficient and selective cleavage of aryl tert-butyldimethysilyl ethers using KOH in ethanol,CHEM. LETT. 2003, 32 (7), 568-569 .(91)Shang, YJ; Shou, WG; Wang, YG,Synthesis of 1,2,4-oxadiazolines on soluble polymer support,Synlett2003, (7), 1064-1066.(92)Zhang, SJ; Dong, JQ; Wang, YG,Synthesis and biological activities of novel seleno epi-daunomycin derivatives,Synth.Commun.2003, 33 (11), 1891-1898.(93)Xu, H; Wang, YG,A rapid and efficient Biginelli reaction catalyzed by zinc triflate,CHIN. J. CHEM.2003, 21 (3), 327-331.(94)Xia, M; Wang, YG,Polyethylene glycol supported chloro[1,3,5]triazine: A novel synthetic auxiliary for the liquid-phase synthesis of alkynyl benzamide derivatives,Synth.Commun.2003, 33 (3), 403-408.(95)Shang, YJ; Wang, YG.One-pot synthesis of isoxazolines using soluble polymer-supported acrylate,CHIN. J. CHEM. 2003, 21 (1), 7-8.(96)Shang YJ,Wang YG*, Soluble polymer-supported synthesis of isoxazoles,Tetrahedron Lett.2002,43(12), 2247-2249.(97)Xia M,Wang YG*, Soluble polymer-supported synthesis of Biginelli compounds,Tetrahedron Lett.2002,43(43), 7703-7705.(98)Shang YJ,Wang YG*, Synthesis of isoxazolines and isoxazoles using poly(ethylene glycol) as support,Synthesis2002, (12), 1663-1668.(99)Zhang SJ, Jia ZP,Wang YG*, Design, synthesis and antitumor activities of novel 7-arylseleno-7-deoxy-daunomycinone derivatives,Bioorganic & Medicinal Chem.2002,10(12), 3899-3904.(100)Zhang, SJ; Wang, YG, A facial synthesis of 7-selenodaunomycinone derivatives,J. CHEM. RES.-S2001, (12), 520-521.
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