In recent years, due to the popularization of higher education, our graduates continue to increase, their number has grown from 1.07 million in 2000 reached 610 million in 2009. However, with continued growth in the total opposite of college graduates is that the jobs market, the demand on the number of college students significantly reduced, the labor market supply and demand imbalance, the structural contradiction, resulting in poor channels of employment, college graduates Employment has become a social problem. With the popularity of the Internet, electronic age, the number of Chinese Internet users has grown more and more extensive network of surface effects. Online shopping as an emerging consumer fashion, this one contains enormous business opportunities. Due to this reality, students venture into a new network of social issues, on the one hand it is largely resolved from the employment of college students, to promote employment, entrepreneurship, while it also led the development of electronic commerce. Students network business in various forms, compared to re-design of new models, build new platforms or systems, provide new services to other network business model, C2C (Consumer to Consumer, or individual personal e-commerce), "Internet sales "business model for its popularity, universality, less investment and lower the threshold of the many advantages of a network of entrepreneurial students preferred. However, students start the process in the network will encounter financial, personnel, supply and so difficult, and the lack of experience and good grasp business direction, the lack of toughness and so on. Faced with these issues, both college students, I need to strengthen their ability to acquire more experience and lessons, but also need social, government and universities in various aspects of the policies introduced to encourage, support network of business students. This would enable the students the meaning and value of Internet businesses maximize. And, with the continuous optimization of business environment, students will become future Internet business trends in entrepreneurship among university students.