matter发表研究论文

近期， 武汉 科技 大学“超分子材料与分子纳米器件团队”梁峰教授课题组 以合成化学作为基础和核心，积极拓展与相关学科和领域的交叉融合，在新材料精准化制备和应用研究方向取得进展，发表了多篇高水平研究论文。

利用金纳米颗粒的可塑性， 梁峰教授课题组可控制备了低钯含量的星状金钯双金属纳米颗粒 。通过对金钯双金属纳米星的中间产物的系列表征， 提出了金钯纳米星“两步法”的生长机理：即先形成单金属金纳米球，再以此为核心形成双金属金钯纳米星。 由于纳米颗粒中钯元素的加入，该纳米颗粒不仅能够高效催化对硝基苯酚（工业废料）还原为对氨基苯酚（工业原料），还能够有效催化Suzuki偶联反应， 实现催化剂的多功能化 。研究成果 “ Au-Pd nanostars with low Pd content : controllable preparation and remarkable performance in catalysis ”在《 The Journal of Physical Chemistry C 》杂志发表。化学与化工学院2017级博士研究生马涛是该论文的第一作者。

金钯双金属纳米颗粒的可控制备及多功能催化示意图

通过将石墨烯气凝胶引入掺杂有聚多巴胺纳米颗粒（PDA-NPs）的聚（N-异丙基丙烯酰胺）（PNIPAM）网络中，梁峰教授课题组与国家纳米科学中心韩东研究员课题组合作，制备出了一种多功能水凝胶 。除了增强的机械性能、良好的导电性能和自粘附性能， 制备得到的水凝胶还表现出近红外和温度双响应性能，可以根据需要释放药物；并且，在药物释放过程中，水凝胶的电阻也随之变化，因此可以利用电阻变化来实时监测药物的释放浓度。 这使得其在药物可控载释和精准医疗等领域具有潜在的应用价值。研究结果“ Temperature/Near-Infrared-Responsive Conductive Hydrogel for Controlled Drug Release and Real-Time Monitoring ” 在《 Nanoscale 》杂志发表。化学与化工学院2016级博士研究生朱玉亭是该论文的第一作者。

在以农药为主的农业化学品的实际应用中，促进药液喷雾在目标作物上的铺展和沉积对提高农药使用效率，降低对环境影响具有重要意义。柱芳烃(Pillar[n]arene)是一类新型大环超分子主体。与传统的大环结构相比，柱芳烃具有高度对称的刚性骨架结构和独特的富电子空腔并易于衍生化，在超分子化学领域表现出了重要的应用价值。 梁峰教授课题组与华中师范大学李海兵教授课题组合作 ， 利用柱芳烃与农药分子间的主-客相互作用成功实现了农药分子矮壮素液滴在疏水表面上的铺展和沉积，并表现出优异的选择性 。这一研究 探索 了超分子化学在农业领域的应用，并对实现农药的精细利用具有指导意义。研究结果“ Pillar[5]arene promoted selective spreading of chlormequat droplets on hydrophobic surface ”在《 Langmuir 》杂志发表。化学与化工学院2017级硕士研究生余胜是该论文的第一作者。

此外，该团队硕士研究生王娇（导师为陈荣生教授）和曾艳教授团队合作研究的论文“ Catalyst-free fabrication of one-dimensional N-doped carbon coated TiO2 nanotube arrays by template carbonization of polydopamine for high performance electrochemical sensors ”在《 Applied Surface Science 》杂志发表。博士后张雄志（合作导师为刘思敏教授）等的研究论文“ Host-guest interaction-mediated fabrication of hybrid microsphere-structured supramolecular hydrogel showing high mechanical strength ”在《 Soft Matter 》杂志发表。

上述论文的第一单位为武汉 科技 大学省部共建耐火材料与冶金国家重点实验室。研究工作得到国家高层次人才计划、国家自然科学基金、湖北省楚天学者计划、湖北省高等学校优秀中青年 科技 创新团队项目、省部共建耐火材料与冶金国家重点实验室、煤转化与新型炭材料湖北省重点实验室、武汉 科技 大学优秀博士论文培育项目的资助。

来源 武汉 科技 大学

论文链接

近五年作为通讯作者，共发表了研究论文200余篇，其中被SCI收录180余篇，主要发表在国际著名的Adv. Funct. Mater.、Chem: Eur.J.、Chem. Commun.、J. Mater. Chem.、 J. Phys. Chem. B、J. Phys. Chem. C、J. Comput. Chem.、Inorg. Chem.、Appl. Catal. B、Nanotechnology、J. Phys.: Condensed Matter等学术期刊上，影响因子在3.0以上的论文有50余篇，其中影响因子在5.0以上8篇。成果被SCI收录期刊正面引用1400余次。出版专著两部，美国科学出版社邀请为纳米科学技术大百科全书撰写了完整的一章。申请发明专利14项。已发表和已录用的主要论文清单如下（以下均为SCI期刊收录论文，*代表通讯联系人）·Pan Qing-Jiang,Guo Yuan-Ru,Li Li,Fu Hong-Gang*,and Zhang Hong-Xing “Structures,Spectroscopic Properties and Redox Potentials of Quaterpyridyl Ru（Ⅱ） Photosensitizer and its Derivatives for Solar Energy Cell: A Density Functional Study” Physical Chemistry Chemical Physics 2011,DOI:10.1039/C1CP00030F.·Gao Xiao-Qin,Pan Qing-Jiang,Li Li,Guo Yuan-Ru,Zhang Hong-Xing,Fu Hong-Gang* “Structures and Spectroscopic Properties of Ruthenium Phenanthroline Solar-Cell Sensitizers: A Computational Study” Chemical Physics Letters,2011,506,146-151.·Zhou W,Sun FF,Pan K,Tian GH,Fu HG*. Well-ordered large-pore mesoporous anatase TiO2 with remarkably high thermal stability and improved crystallinity: Preparation,characterization and photocatalytic performance. Advanced Functional Materials,2011,21,1922-1930..·Jiang Baojiang,Tian CG,Fu Honggang*,et al. In-Situ Growth of TiO2 in Interlayers of Expanded Graphite for the Fabrication of TiO2-Graphene with Enhanced Photocatalytic Activity. Chemistry-A European Journal,2011,Accepted,chem.201100250.· Li Sun,Chungui Tian,Lei Wang,Jinlong Zou,Guang Mu,Honggang Fu*,Magnetically Separable Porous Graphitic Carbon with Large Surface Area as Excellent Adsorbents for Metal Ions and Dye. Journal of Materials Chemistry,2011,2011,21,7232-7239.· Zhao H,Yang J,Wang L,Tian CG,Jiang BJ,Fu HG*. Fabrication of palladium nanoparticles/graphene nanosheets hybrid via sacrifice of copper template and its application in catalytic oxidation of formic acid. Chemical Communications,2011,47,2014-2016.· Yang J,Tian CG,Wang L,Fu HG*. An effective strategy to small-sized and high-dispersed palladium nano particles supported on graphene with excellent performance for formic acid oxidation. Journal of Materials Chemistry,2011,21,3384-3390.· Tian GH,Chen YJ,Zhou W,Ren ZY,Tian CG,Fu HG*. Facile solvothermal synthesis of hierarchical flower-like Bi2MoO6 hollow spheres as high performance visible-light driven photocatalysts. Journal of Materials Chemistry,2011,21,887 – 892.· Hu ZF,Shen PK*,Fu HG*,et al. Oxygen Reduction Electrocatalysis Enhanced by Nanosized Cubic Vanadium Carbide. Electrochemistry Communications,2011,Accepted,ELECOM 3881.· Tian Guohui,Chen Yajie,Zhou Wei,Pan Kai,Huang Xu-ri and Fu Honggang *,3D hierarchical flower-like TiO2 nanostructure: morphology control and its photocatalytic property. CrstEngComm,2011,13,2994.· Dong Youzhen,Pan Kai,Zhou Wei,Pan Qingjiang,Xie Tengfeng,Wang Dejun,Fu Honggang*,Dye-sensitized solar cells based on TiO2-B nanobelt/TiO2 nanoparticle sandwich-type photoelectrodes with controllable nanobelt length. Dalton Transactions,2011,40,3808–3814.· Cai ZC,Tian CG,Wang L,Zhou W,Wang BL,Fu HG*. One-pot synthesis of silver particle aggregation as highly active SERS substrate. Journal of Raman Spectroscopy,2011,1,5-11.· Tian CG,Li W,Fu HG*,et al. Glucose-mediated solution-solid route for easy synthesis of Ag/ZnO particles with superior photocatalytic activity and photostability，Journal of Alloys and Compounds，2011,509,6935-6941.· Tian CG,Li W,Fu HG*,et al. Controllable Fabrication of Various ZnO Micro/nanostructures from a Wire-like Zn-EG-AC Precursor via a Facile Solution-based Route，Materials Research Bulletin，2011，MRB5116.· Zhao H,Fu HG,Tian CG,et al.Facile shape-controlled synthesis of palladium nanostructures on copper for promising Surface-enhanced Raman scattering,MATERIALS LETTERS,2010,64,2255-2257· Zhao H,Fu HG,Tian CG,et al. Fabrication of silver nanoparticles/single-walled carbon nanotubes composite for surface-enhanced Raman scattering,JOURNAL OF COLLOID AND INTERFACE SCIENCE,2010,351,343-347.· Jiang BJ,Tian CG,Fu HG*,et al. Facile Fabrication of High Quality Graphene from Expandable Graphite: Simultaneous Exfoliation and Reduction. Chemical Communication. 2010,46,4920 - 4922.· Feng SS,Ren ZY,Fu HG*,et al. Synthesis and application of hollow magnetic graphitic carbon microspheres with/without TiO2 nanoparticle layer on the surface. Chemical Communication. 2010,46,6276-6278.· Liu Y,Ren ZY,Fu HG*,et al. Synthesis and applications of graphite carbon sphere with uniformly distributed magnetic Fe3O4 nanoparticles (MGCSs) and MGCS@Ag,MGCS@TiO2. Journal of Material Chemistry 2010,20，4802- 4808.· Wang L,Tian CG,Fu HG*,et al. Mass production of graphene via an in situ self-generating template route and its promoted activity as electrocatalytic support for methanol electroxidization. Journal of Physical Chemistry C 2010,114 （19），8727–8733.· Qu Y,Zhou W,Fu HG*,et al. Hierarchical anatase TiO2 porous nanopillars with high crystallinity and controlled length: An effective candidate for dye-sensitized solar-cells. Physical Chemistry Chemical Physics 2010,12,9205 - 9212.· Wang BL,Tian CG,Fu HG,et al. Chitosan: a green carbon source for the synthesis of graphitic nanocarbon,tungsten carbide and graphitic nanocarbon/tungsten carbide composites. Nanotechnology 21 （2010） 025606 （9pp).· Li YJ,LV RJ,Fu HG*,et al. Fabrication and evaluation of chiral monolithic column modified by β-cyclodextrin derivatives. Talanta 80 （2010） 1378–1382· Zhou W,Pan K,Fu HG*,et al. Photodegradation of organic contamination in wastewaters by bondingTiO2/single-walled carbon nanotube composites with enhanced photocatalytic activity. Chemosphere 81 （2010） 555–561.· Guohui Tian,Chen Yajie,Pan Kai,Fu Honggang*，Efficient visible light-induced degradation of phenol on N-doped anatase TiO2 with large surface area and high crystallinity. Applied Surface Science 2010,256,3740-3745.· Tian CG,Li W,Fu HG*,et al. One-pot Synthesis of the Ag Nanoparticles modified ZnO Microspheres in Ethylene Glycol Medium and Their Enhanced Photocatalytic Performance. Journal of Solid State Chemistry,2010,183,2720-2725.· Zhou W,Pan K,Fu HG*,et al. The sandwich structure electrodes based on wire-likeTiO2–β-cyclodextrin–SWCNT composite for dye-sensitized solar cells. Journal of Photochemistry and Photobiology A: Chemistry 2009,207,306–310.· Tian XQ,Wan LJ,Fu HG*,et al. Facile synthesis of mesoporous ZnAl2O4 thin films through the evaporation-induced self-assembly method. Journal of Alloys and Compounds 2009,488,320–324.· Wang RH,Tian CG,Fu HG*,et al. In situ simultaneous synthesis of WC/graphitic carbon nanocomposite as a highly efficient catalyst support for DMFCw. Chemical Communication 2009,3104-3106.· Pan QJ,Fu HG*,Zhang HX*,et al. Theoretical Studies on Metal−Metal Interaction,Excited States,and Spectroscopic Properties of Binuclear Au−Au,Au−Rh,and Rh−Rh Complexes with Diphosphine Ligands: Buildup of Complexity from Monomers to Dimers. Inorganic Chemistry,2009,48,2844–2854.· Zhou W,Pan K,Fu HG*,et al. Solar-induced Self-assembly of TiO2-β-cyclodextrin-MWCNT Composite Wires. Physical Chemistry Chemical Physics 2009,11,1713-1718.· Kang CH,Jing LQ*,Fu HG*,et al. Mesoporous SiO2-Modified Nanocrystalline TiO2 with High Anatase Thermal Stability and Large Surface Area as Efficient Photocatalyst. Journal of Physical Chemistry C 2009,113,1006–1013.· Wang BL,Tian CG,Fu HG*,et al. A simple and large-scale strategy for the preparation of Ag nanoparticles supported on resin-derived carbon and their antibacterial properties. Nanotechnology 2009,20,025603（7pp）· Tian GH,Fu HG*,Jing LQ,et al. Synthesis and photocatalytic activity of stable nanocrystalline TiO2 with high crystallinity and large surface area. Journal of Hazardous Materials 2009,161,1122-1130.· Zhang GX,Yu HT*,Fu HG,et al. First-principles calculations of the stability and electronic properties of the PbTiO3 （110） polar surface. Journal of Computational Chemistry 2009,30,1785-1798.· Tian GH,Pan K,Fu HG*,et al. Enhanced photocatalytic activity of S-doped TiO2-ZrO2 nanoparticles under visible-light irradiation. Journal of Hazardous Materials 2009,166,939-944.· Pan K,Dong YZ,Fu HG*,et al. TiO2-B narrow nanobelt/TiO2 nanoparticle composite photoelectrode for dye-sensitized solar cells. Electrochimica Acta 2009,54,7350-7356.· Kan K,Fu HG,Shi KY*,et al. Amidation of single-walled carbon nanotubes by a hydrothermal process for the electrooxidation of nitric oxide. Nanotechnology 2009,20,185502 （7pp).· Wang L,Tian CG,Fu HG*,et al. Controllable Synthesis of Graphitic Carbon Nanostructures from Ion-Exchange Resin-Iron Complex via Solid-State Pyrolysis Process. Chemical Communication 2008,5411-5413.· Zhou W,Fu HG*,Pan K,et al. Mesoporous TiO2/α-Fe2O3: Bifunctional Composites for Effective Elimination of Arsenite Contamination through Simultaneous Photocatalytic Oxidation and Adsorption. Journal of Physical Chemistry C 2008,112,19584-19589.· Liu KS,Fu HG*,Xie Y,et al. Assembly of β-Cyclodextrins Acting as Molecular Bricks onto the Multiwall Carbon Nanotubes.Journal of Physical Chemistry C 2008,112,951-957.· Tian GH,Fu HG*,Jing LQ,et al. Preparation and Characterization of Stable Biphase TiO2 Photocatalyst with High Crystallinity,Large Surface Area and Enhanced Photoactivity. Journal of Physical Chemistry C 2008,112,3083-3089.· Zhou W,Liu KS,Fu HG*,et al. Multi-modal mesoporous TiO2–ZrO2 composites with high photocatalytic activity and hydrophilicity. Nanotechnology 2008,19,035610（7pp).· Pan QJ,Zhou X,Fu HG*,et al，“Isovalent Gold(I),-（Ⅱ），and -（Ⅲ） and Mixed-Valent Gold(I)/Gold（Ⅲ） Phosphorus Ylide Complexes. Combined ab Initio and Density Functional Study of Electronic Structures and Spectroscopic Properties” Organometallics 2008,27,2474–2482.· Wan LJ,Fu HG*,Shi KY,et al. Facile synthesis of ordered nanocrystalline alumina thin films with tunable mesopore structures. Microporous and Mesoporous Materials 2008,115（3），301-307.· Pan QJ，Zhou X,Fu HG*,et al. A theoretical probe on the ground- and excited-state properties of heterobinuclear Au–Pt complex with phosphine ligands. Comparison with analogous homobinuclear Au–Au and Pt–Pt complexes. Chemical Physics Letters 2008,453,7-12.· Jing LQ*,Li SD,Fu HG*,et al. Investigation on the electron transfer between anatase and rutile in nano-sized TiO2 by means of surface photovoltage technique and its effects on the photocatalytic activity. Solar Energy Materials & Solar Cells 2008,92,1030– 1036.· Wan LJ,Fu HG*,Shi KY,et al. Facile synthesis of iron oxide with wormlike morphology and their application in water treatment. Journal of Solid State Chemistry 2008,181（4），735-740.· Chi YJ,Fu HG*,Qi LH,et al. Preparation and photoelectric performance of ITO/TiO2/CdS composite thin films. Journal of Photochemistry and Photobiology A: Chemistry 2008，195（2-3），357-363.· Xie Y,Yu HT,Fu HG*,et al. Lattice dynamics investigation on different transition behaviors of cubic BaTiO3 and SrTiO3 by first-principles calculatoins. J. Phys.: Condens. Matter,2008,20,215215 （8pp)· Wan LJ,Fu HG*,Shi KY,et al. Simple synthesis of mesoporous alumina thin films.Material Letters 2008,62（10-11），1525-1527.· Song S,Jing LQ*,Fu HG*,et al. Superhydrophilic anatase TiO2 film with the micro- and nanometer-scale hierarchical surface structure. Materials Letters 2008,62,3503–3505.· Zhu YJ,Yuan FL*,Fu HG,et al. Direct NO decomposition over La2-xBaxNiO4 catalysts containing BaCO3 phase. Appl. Catal B-Environ 2008,82,255-263.· Li MX,Zhang HX*,Fu HG,et al. Theoretical Studies of Electronic Structuresand Spectroscopic Properties of Ru Complexes. Inorg. Chem 2008 47（7），2312-2324.· Xie Y,Yu HT,Fu HG*,A First-Principles Investigation of Stability and Structural Properties of the BaTiO3 （110） Polar Surface. Journal of Physical Chemistry C,2007,111,6343-6349.· Kan W,Yu HT,Fu HG*,et al. Theoretical investigation on the protonation reactions and products of the stable [N,C,C,S] isomers,Journal of Computational Chemistry,2007,28,2472-2482.· Zhao YL,Yu HT*,Fu HG,et al. Combined DFT,QCISD(T),and G2 mechanism investigation for the reactions of carbon monophosphide CP with unsaturated hydrocarbons allene CH2CCH2 and methylacetylene CH3CCH,Journal of Computational Chemistry,2007,28,1221-1233.· Pan QJ,Zhang HX*,Fu HG,et al. Electronic Structures and Spectroscopic Properties of Mono- and Binuclear d8 Complexes: a Theoretical Exploration on Promising Phosphorescent Materials. Journal of Physical Chemistry A,2007,111（2）; 287-294.· Pan QJ,Zhou X,Fu HG*,et al. Theoretical studies on spectroscopic properties of binuclear palladium（Ⅱ） halide with phosphine ligands Journal of Photochemistry and Photobiology A: Chemistry,2007,188（2-3），287-292.· Xie Y,Fu HG*,Yu HT,et al. A first-principles investigation into the ferroelectric and antiferrodistortive instabilities of cubic SrTiO3,Journal of Physics: Condensed Matter,2007,19,506213（9pp)· Pan QJ,Zhou X,Fu HG*,et alStructures and electronic spectra of [Pt2(P2O5H2）4X2]4– (X = Cl,Br and I): a comparative study of ab initio and density functional theory Inorganic Chemistry Communications 2007,10,183–186.· Li SD,Jing LQ,Fu HG*,et al. Photoinduced charge property of nanosized perovskite-type LaFeO3 and its relationships with photocatalytic activity under visible irradiation. Materials Research Bulletin 2007,42,203-212.· Yang PP,Fu HG,Lin J*,et al. MCM-41 functionalized with YVO4: Eu3+: a novel drug delivery system. Nanotechnology 2007,18,235703（6pp).· Yang PP,Fu HG,Lin J*,et al. Luminescence functionalization of SBA-15 by YVO4: Eu3+ as a novel drug delivery system. Inorg. Chem. 2007,46,3202-3211.· Jing LQ,Fu HG*,Wang BQ,et al. Effects of Sn dopant on the photoinduced charge property and photocatalytic activity of TiO2 nanoparticles. Applied Catalysis B,2006,62,282-291.· Jing LQ,Xin BF,Fu HG*,et al. Effects of Surface Oxygen Vacancies on Photophysical and Photochemical Processes of Zn-Doped TiO2 Nanoparticles and Their Relationships. Journal of Physical Chemistry B2006,110,17860-17865.· Pan QJ,Fu HG*,Yu HT,et al. A Theoretical Insight Into Electronic Structures and Spectroscopic Properties of [Pt2(pop)4]4–，[Pt2(pcp)4]4– and Related Derivatives (pop = P2O5H22– and pcp = P2O4CH42–） Inorganic Chemistry，2006,45（21），8729–8735.· Liu KS,Zhou W,Fu HG*,et al. Influence of calcination temperatures on the photocatalytic activity and photo-induced hydrophilicity of wormhole-like mesoporous TiO2. Nanotechnology 2006,17,1363-1369.· Liu KS,Fu HG*,Shi KY,et al. Hydrophilicity and formation mechanism of large-pore mesoporous TiO2 thin films with tunable pore diameters. Nanotechnology 2006,17,3641-3648.· Pan QJ,Zhang HX*,Fu HG,et al “Theoretical Studies on Metal–Metal Interaction and Intrinsic 1,3[σ*(d）σ（s/p)] Excited States of Binuclear d10 Complexes with Bridging Phosphine Ligands” European Journal of Inorganic Chemistry 2006 （5），1050-1059.· Jing LQ,Wang DJ,Fu HG*,et al. Effects of noble metal modification on surface oxygen composition,charge separation and photocatalytic activity of ZnO nanoparticles. Journal of Molecular Catalysis A 2006,244,193-200.· Pan QJ,Fu HG*,Yu HT,et al Substituent effect on the structure and luminescence of binuclear Au(I) complexes: An ab initio study. Chemical Physics Letters 2006,426（4-6），257-262.· Jing LQ,Qu YC,Fu HG*,et al. Review of photoluminescence performance of nano-sized semiconductor materials and its relationships with photocatalytic activity. Solar Energy Materials & Solar Cell 2006,90,1773-1787.· Pan QJ,Fu HG*,Yu HT,et al Spectroscopic Properties of Mono- and Binuclear Platinum（Ⅱ） Alkynyl Complexes with Phosphine Ligands: A Theoretical StudyInorganica Chimica Acta 2006,359（10），3306–3314.· Wang BQ,Jing LQ,Fu HG*,et al. Enhancement of the photocatalytic activity of TiO2 nanoparticles by surface-capping DBS groups. Applied Surface Science 2006,252,2817-2825.· Liu KS,Zhang ML,Fu HG*,et al. Uniform TiO2 thin films with anatase nanocrystallites synthesized through evaporation-induced assembly. Journal of Non-Crystalline Solids 2006,352,2284–2287.· Liu KS,Fu HG*,Shi KY,et al. Preparation of large-pore mesoporous nanocrystalline TiO2 thin films with tailored pore diameters. Journal of Physical Chemistry B 2005,109 （40），18719-18722.· Shi KY,Chi YJ,Fu HG*,et al. Controlled growth of mesostructured crystalline iron oxide nanowires and Fe-filled carbon nanotube arrays templated by mesoporous silica SBA-16 film. Journal of Physical Chemistry B2005,109 （7），2546-2551.· Xin BF,Jing LQ,Fu HG*,et al. Effects of simultaneously doped and deposited Ag on the photocatalytic activity and surface states of TiO2. Journal of Physical Chemistry B2005,109,2805-2809.· Liu KS,Zhang ML,Fu HG*,et al. Preparation,characterization,and photo-induced hydrophilicity of nanocrystalline anatase thin films synthesized through evaporation-induced assembly. Nanotechnology 2005,16,3006-3011.· Xin BF,Ren ZY,Fu HG*,et al. Photocatalytic activity and interfacial carrier transfer of Ag–TiO2 nanoparticle films. Applied Surface Science 2005,252,2050–2055.· Liu KS,Zhang ML,Fu HG*,et al. Large pore mesoporous nanocrystalline titania thin films synthesized through evaporation-induced self-assembly. Materials Letters 2005,59,3308 -3310.